| 129 | 0 | 41 |
| 下载次数 | 被引频次 | 阅读次数 |
利用废弃红砖粉作为复合催化剂载体，通过酸、水热和掺杂生物炭活化等方法，制备金属镍改性的红砖粉基生物炭催化剂。结果表明：在优化制备条件下，该催化剂具有大比表面积和弱酸酸性特征，有效提高了对H2的选择性。在催化玉米秸秆热解过程中，实现了高达65.5%的产气率和73.64 mL/g的H2产率，较无催化剂条件显著提升31.82%。本研究不仅为废弃红砖粉的环保再利用提供了新途径，也为生物质能源的高效转化提供了技术支持，具有重要的环境和经济意义。
Abstract：In this study, red brick powder was utilized as a composite catalyst carrier to prepare nickel-modified red brick powder-based biochar catalysts through acid activation, hydrothermal treatment, and doping with biochar. Results demonstrate that under optimized preparation conditions, the catalyst exhibits a large specific surface area and weakly acidic properties, which effectively enhance hydrogen selectivity. During the catalytic pyrolysis of corn stover, the catalyst achieved a remarkable gas production rate of 65.5% and hydrogen yield of 73.64 mL/g, representing a significant 31.82% improvement compared to non-catalytic conditions. This research not only provides an environmentally friendly recycling approach for waste red brick powder but also offers technical support for efficient conversion of biomass energy, demonstrating substantial environmental and economic significance.
[1]郑璐.基于河流型湿地生态修复的湿地公园生态修复研究——以长白山碱水河国家湿地公园为例[J].森林防火,2023,41(03):117-119.
[2]AKTER M M,SUROVY I Z,SULTANA N,et al.Techno-economics and environmental sustainability of agricultural biomass-based energy potential[J].Applied Energy,2024,(359):122662.
[3]麻馨月.工业木质素结构表征及催化降解研究[J].林产工业,2024,61(12):19-25.
[4]官铁辉.始兴县森林资源管理现状与对策[J].森林防火,2024,42(02):117-119.
[5]WANG Z,BURRA K G,ZHANG M,et al.Co-pyrolysis of waste tire and pine bark for syngas and char production[J].Fuel,2020,(274):117878.
[6]HU Q,ZHANG H,MAO Q,et al.The effect of co-pyrolysis of bamboo waste and polypropylene on biomass deoxygenation and carbonization processes[J].Energy,2024,(291):130339.
[7]TIWARI M,DIRBEBA M J,LEHMUSTO J,et al.Analytical and applied pyrolysis of challenging biomass feedstocks:Effect of pyrolysis conditions on product yield and composition[J].Journal of Analytical and Applied Pyrolysis,2024,(177):106355.
[8]BIANASARI A A,KHALED M S,HOANG T D,et al.Influence of combined catalysts on the catalytic pyrolysis process of biomass:A systematic literature review[J].Energy Conversion and Management,2024,(309):118437.
[9]YE J,XIAO J,HUO X,et al.Effect of CO2 atmosphere on biomass pyrolysis and in-line catalytic reforming[J].International Journal of Energy Research,2020,44(11):8936-8950.
[10]CHEN W,CHEN Y,YANG H,et al.Investigation on biomass nitrogen-enriched pyrolysis:Influence of temperature[J].Bioresource Technology,2018,(249):247-253.
[11]CHANDLER D S,SEUFITELLI G V S,RESENDE F L P.Catalytic route for the production of alkanes from hydropyrolysis of biomass[J].Energy&Fuels,2020,34(10):12573-12585.
[12]张成博,罗希,屈庆熙,等.飞灰基HZSM-5催化松木热解选择性制备芳烃[J].新能源进展,2024,12(04):365-372.
[13]CHEN X,CHEN Y,YANG H,et al.Fast pyrolysis of cotton stalk biomass using calcium oxide[J].Bioresource Technology,2017,(233):15-20.
[14]XIA S,YANG H,LEI S,et al.Iron salt catalytic pyrolysis of biomass:Influence of iron salt type[J].Energy,2023,(262):125415.
[15]SANTOSA D M,ZHU C,AGBLEVOR F A,et al.In situ catalytic fast pyrolysis using red mud catalyst:impact of catalytic fast pyrolysis temperature and biomass feedstocks[J].ACS Sustainable Chemistry&Engineering,2020,8(13):5156-5164.
[16]FERREIRA A F,SOARES DIAS A P.Pyrolysis of microalgae biomass over carbonate catalysts[J].Journal of Chemical Technology&Biotechnology,2020,95(12):3270-3279.
[17]LU Q,LI W,ZHANG X,et al.Experimental study on catalytic pyrolysis of biomass over a Ni/Ca-promoted Fe catalyst[J].Fuel,2020,(263):116690.
[18]刘乐桐,王雯,代建军,等.玉米秸秆催化热解制取富氢气体[J].可再生能源,2023,41(11):1421-1429.
[19]胡亚风,魏洋,闫亚东,等.玉米秸秆粉级配及其孔隙特性试验研究[J].森林工程,2021,37(01):111-116.
[20]郭明辉,李嘉兴,唐宽勇.生物质固体成型燃料研究进展[J].林产工业,2023,60(10):40-44.
[21]李翔宇,李学琴,段喜鑫,等.废弃红砖粉催化生物质焦油热解的可行性[J].北华大学学报(自然科学版),2022,23(06):809-814.
[22]DONG Q,ZHANG S,LI H,et al.Catalytic cracking of biomass tar together with syngas production over red brick powder-supported nickel catalysts[J].Fuel Processing Technology,2019,(194):106123.
[23]LI X,LIU P,YANG Y,et al.Pyrolysis behaviors of biomass tar-related model compounds catalyzed by Ni-modified HZSM-5 molecular sieve[J].Industrial Crops and Products,2023,(199):116743.
[24]SANTAMARIA L,LOPEZ G,ARREGI A,et al.Stability of different Ni supported catalysts in the in-line steam reforming of biomass fast pyrolysis volatiles[J].Applied Catalysis B:Environmental,2019,(242):109-120.
[25]ARREGI A,LOPEZ G,AMUTIO M,et al.Kinetic study of the catalytic reforming of biomass pyrolysis volatiles over a commercial Ni/Al2O3 catalyst[J].International Journal of Hydrogen Energy,2018,43(27):12023-12033.
[26]JINDAL M,PALLA V C S,THALLADA B.Effect of zeolite structure and Si/Al ratio on cotton stalks hydropyrolysis[J].Bioresource Technology,2023,(376):128933.
[27]JAHROMI H,AGBLEVOR F A.Hydrodeoxygenation of pinyon-juniper catalytic pyrolysis oil using red mud-supported nickel catalysts[J].Applied Catalysis B:Environmental,2018,(236):1-12.
[28]吴佳伟,王志伟,陈高峰,等.基于镍基催化剂的生物质催化热解制氢研究进展[J/OL].化工新型材料,2024-10-25[2025-02-17].https://doi.org/10.19817/j.cnki.issn1006-3536.2025.03.025.
[29]SUN H,SUN S,FENG D,et al.Mechanism of coke formation and corresponding gas fraction characteristics in biochar-catalyzed tar reforming during corn straw pyrolysis[J].Fuel Processing Technology,2021,(221):106903.
[30]LI J,XU K,YAO X,et al.Investigation of biomass slow pyrolysis mechanisms based on the generation trends in pyrolysis products[J].Process Safety and Environmental Protection,2024,(183):327-338.
[31]LI A,HAN H,ZHENG K,et al.Sludge pyrolysis integrated biomass gasification to promote syngas:Comparison of different biomass[J].Science of The Total Environment,2024,(908):168278.
[32]SHAYAN E,ZARE V,MIRZAEE I.Hydrogen production from biomass gasification; a theoretical comparison of using different gasification agents[J].Energy Conversion and management,2018,(159):30-41.
[33]HE R,DENG J,DENG X,et al.Effects of alkali and alkaline earth metals of inherent minerals on Fe-catalyzed coal pyrolysis[J].Energy,2022,(238):121985.
基本信息:
DOI：10.19531/j.issn1001-5299.202512005
中图分类号:S216.2;TK6
引用信息:
[1]张芯禹,王明浩,李学琴,等.红砖粉掺杂生物炭载镍催化玉米秸秆热解产氢研究[J].林产工业,2025,62(12):28-35.DOI:10.19531/j.issn1001-5299.202512005.
基金信息:
吉林省科技发展计划项目（YDZJ202301ZYTS485）; 北华大学研究生创新计划项目（研创合字[2024]048）